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Effect of low-temperature treatments on photoluminescence enhancement of ion-beam synthesized Si nanocrystals in SiO₂ matrix

机译:低温处理对SiO 2基体中离子束合成的Si纳米晶体光致发光增强的影响

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摘要

The results of experimental researches of photoluminescence (PL) spectra inudSi nanocluster structures obtained by implantation of silicon ions to SiO₂-Si structuresudwith high-temperature (1100 °C) and following low-temperature annealings in variousudregimes are given. We have found that additional low-temperature treatments in definiteudregimes result in substantial increase of the PL intensity, thus a maximum effect isudobserved after annealing in air. The possible mechanisms of the obtained effects areuddiscussed. Those are based on supposition about the dominating contribution ofudluminescence through the electronic states on SiO₂-Si nanoclaster interfaces, which isudrelated to defect and impurity complexes. It has been shown that growth of the PLudintensity is governed by two effects: generation of new centers of radiativeudrecombination on the nanocrystal-dielectric matrix interfaces, and passivation of nonradiativeudrecombination centers.
机译:给出了在高温(1100°C)下将硅离子注入到SiO 2 -Si结构 ud中并在各种 udregime下进行低温退火后获得的 udSi纳米簇结构中的光致发光(PL)光谱的实验研究结果。我们已经发现,在确定的 udregimes中进行额外的低温处理会导致PL强度的显着增加,因此在空气中退火后效果最大。讨论了获得效果的可能机制。这些假设是基于关于通过SiO 2 -Si纳米壳界面上的电子态的发荧光的主要贡献的假设,这与缺陷和杂质配合物有关。已经显示出PL 强度的增长受两个效应支配:在纳米晶体-介电基体界面上产生新的辐射 udrecombination中心,以及钝化非辐射 udrecombination中心。

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