Radiation Polymerization of Oligo(Ethyleneglycol-Maleate-Adipate) with Various Monomers

摘要

Radiation copolymerization of oligo(ethyleneglycol-maleate-adipate) with monomers of various structures has been studied. It has been shown that for radiation copolymerization with OMAD, monomers can be arranged in a series according to reaction capability. The cross-linking reaction under the influence of -radiation proceeds more completely than in the presence of peroxide indicators. This is confirmed by data from IR-spectra, results of determination of the gel-fraction content and specific volume of the contraction of the copolymers. Physico-mechanical indices, thermostability and water-resistance in all radiation copolymers studied is higher than in similar copolymers obtained by the thermo-chemical method. (Author)