首页> 外国专利> Preparing oligo- or poly- thiophene compounds, useful e.g. in sensors, comprises converting a thiophene derivative with two leaving groups to a polymerization reactive monomer and polymerizing the first and a second product solution

Preparing oligo- or poly- thiophene compounds, useful e.g. in sensors, comprises converting a thiophene derivative with two leaving groups to a polymerization reactive monomer and polymerizing the first and a second product solution

机译:制备低聚或聚噻吩化合物,例如可用于在传感器中,包括将具有两个离去基团的噻吩衍生物转化为聚合反应性单体,并使第一和第二产物溶液聚合

摘要

Preparing oligo- or poly- thiophene compounds comprises (i) converting at least a dissolved thiophene derivative with two leaving groups to a polymerization reactive monomer; (ii) polymerizing the obtained product solution (1) by adding a solution of at least a catalyst; and (iii) polymerizing the product solution (2) for chain elongation on basis of the same thiophene derivative and/or at least an another thiophene derivative, after the product solution (1). Preparation of oligo- or poly- thiophene compounds comprises (i) converting at least a dissolved thiophene derivative with two leaving groups to a polymerization reactive monomer by (a) mixing a solution of at least a dissolved thiophene derivative with two leaving groups with a solution of a metal organic compound or (b) reacting a solution of at least a dissolved thiophene derivative with two leaving groups with an elementary metal; (ii) polymerizing the obtained product solution (1) by adding a solution of at least a catalyst; and (iii) polymerizing the product solution (2) for the chain elongation on basis of the same thiophene derivative and/or at least an another thiophene derivative, after the product solution (1).
机译:制备低聚噻吩或聚噻吩化合物包括:(i)至少将具有两个离去基团的溶解的噻吩衍生物转化为聚合反应性单体; (ii)通过添加至少一种催化剂的溶液来聚合所获得的产物溶液(1); (iii)在产物溶液(1)之后,基于相同的噻吩衍生物和/或至少另一种噻吩衍生物,聚合产物溶液(2)以进行链伸长。低聚或聚噻吩化合物的制备包括(i)通过(a)将至少具有两个离去基团的噻吩衍生物的溶液与溶液混合,将至少具有两个离去基团的溶解的噻吩衍生物转变为聚合反应性单体。一种金属有机化合物或(b)使至少一种具有两个离去基团的溶解的噻吩衍生物的溶液与基本金属反应; (ii)通过添加至少一种催化剂的溶液来聚合所获得的产物溶液(1); (iii)在产物溶液(1)之后,基于相同的噻吩衍生物和/或至少另一种噻吩衍生物,聚合产物溶液(2)以进行链伸长。

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