Photochemistry of 2-Methylene-1,2,3,4-Tetrahydro-1,4-Methanonaphthalene in Protic Media. A Novel Photoinduced Anti-Markovnikov Addition to the Double Bond.

摘要

Irradiation of 2-methylene-1,2,3,4-tetrahydro-1,4-methanonaphthalene (I) in acidic methanol leads to three products (II), (III), and (IV); the formation of (II) represents a novel anti-Markovnikov addition of methanol across the methylene double bond. (Author)