High Energy Materials. New Preparation Approaches to Nitro and Nitroso Derivatives

摘要

Hydrazine and hydroxylamine efficiently transformed dicyanofuroxan into pyridazino- and oxazinofuroxans. Product identification has clarified the reaction between iodoacetonitrile and silver nitrate. A series of azepne oxides was obtained from peroxidation of aldimine derivatives of diaminomaleonitrile. Nitrobenzofuroxans were peroxidized into polynitrobenzene compounds; benzodifuroxan was peroxidized into 1,2,3,4-tetranitrobenzene. Investigations on 2-nitroso-3-nitrosuccinonitrile, 2,3-dinitrosuccinonitrile and related compounds are underway. (Author)