Surface Supported Gold-Organic Hybrids: On-Surface Synthesis and Surface Directed OrientationSurface Supported Gold-Organic Hybrids: On-Surface Synthesis and Surface Directed Orientation

摘要

The surface-assisted synthesis of gold-organic hybrids on Au (111) and Au (100) surfaces is reported by thermally initiated dehalogenation of chloro-substituted perylene-3,4,9,10-tetracarboxylic acid bisimides (PBIs). Structures and surface-directed alignment of the Au-PBI chains are investigated by scanning tunnelling microscopy in ultrahigh vacuum conditions. Using dichloro-PBI as a model system, the mechanism for the formation of Au-PBI dimer is revealed with scanning tunnelling microscopy studies and density functional theory calculations. A PBI radical generated from the homolytic C一Cl bond dissociation can covalently bind a surface gold atom and partially pull it out of the surface to form stable PBI-Au hybrid species,which also gives rise to the surface-directed alignment of the Au-PBI chains on reconstructed Au (100) surfaces.