As a typical family of functional inorganic polyanionic clusters, polyoxometalates ( POMs) can form su-pramolecular complexes with organic cations through electrostatic interaction, and thus be applied for self - assembly , obtaining diverse hybrid supramolecular structures. This method has not only improved the surface properties of the POMs, but also provided amazing amphiphilic building blocks for the construction of various self - assembled mesostructures. In this review, the author summarized the recent research progress of his group regarding the supra-molecular self - assembly of surfactant - encapsulated POMs (SEPs) in solution and at interface. And hope that the systemic summary could provide helpful reference and perspective for stimulating interests in the design of supramolecular complex as building block, new self - assembly strategy and functionalization for new materials.%多金属氧簇作为一类功能性无机多阴离子,可以通过与有机阳离子的静电作用形成超分子复合物,从而用于自组装体系,获得各种各样杂化超分子结构.这种多阴离子表面修饰的方法一方面改善了多金属氧簇的表面性质,另一方面也为构筑各种超分子组装体提供了新颖结构的两亲性构筑基元并展现了独特的自组装性质.主要总结近年来作者在溶液和界面超分子自组装方面的系统研究成果,期望为超分子复合物设计、纳米尺度结构构筑、组装方法和功能化等方面的发展提供参考和借鉴.
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