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首页> 外文期刊>Russian Journal of General Chemistry >Anionarylation of Acrylic and Methacrylic Acids Derivatives with p- and m-Phenylenebisdiazonium Tetrafluoroborates
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Anionarylation of Acrylic and Methacrylic Acids Derivatives with p- and m-Phenylenebisdiazonium Tetrafluoroborates

机译:对和间苯二甲双重氮四氟硼酸酯的丙烯酸和甲基丙烯酸衍生物的阴离子化

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摘要

Chloro-, bromo- and thiocyanatoarylation of amides and nitriles of acrylic and methacrylic acids with bisdiazonium salts based on m- and p-phenylenediamines have been studied. 3,3'-[1,4(3)-phenylene]bis[2-halopropanamides(nitriles)] and 2-thiocyanato-(2-methyl)-3-[4(3)-thiocyanatophenyl]propinamides have been obtained as bishaloarylation and monothiocyanatoarylation products, respectively.
机译:研究了基于间苯二胺和对苯二胺的双重氮盐对丙烯酸和甲基丙烯酸的酰胺和腈的氯,溴和硫氰基芳基化反应。已获得3,3'-[1,4(3)-亚苯基]双[2-卤代丙烷酰胺(腈)]和2-硫氰酸根-(2-甲基)-3- [4(3)-硫氰酸根苯基]丙酰胺,分别是双卤代芳基化和单硫代氰基芳基化的产物。

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