Colloid and Nanosized Catalysts in Organic Synthesis: V. Reactions of Alkyl Halides and Alcohols with beta-Diketones in the Presence of Metal Nanoparticles

摘要

Reaction of copper, nickel, and iron nanoparticles with beta-diketones directly yields corresponding metal beta-diketonates. Reaction of alkyl halides, beta-diketones, and nanodispersed metals leads to a mixture of monoketone and the alkylated beta-diketone. When alcohol is used as the alkylating agent instead of alkyl halide, corresponding ester is formed.