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Thermoluminescent dosimetric properties of CaF2:Tm produced by combustion synthesis

机译:燃烧合成产生的CaF2:Tm的热发光剂量学性质

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Calcium Fluoride is one of the oldest known thermoluminescent materials and is considered to be one of the most sensitive. This work presents the dosimetric properties results of CaF2:Tm produced by combustion synthesis. The X-ray diffraction confirmed that CaF2 was successfully produced. TL emission spectra, obtained using a Hammamatsu optical spectrometer, have the same lines of commercial CaF2:Tm, although transitions P-3(0) -> F-3(4) (455 nm) and (1)G(4) -> H-3(6) (482 nm) are shown to be proportionally more intense. The deconvolution technique was employed and seven glow peaks were found similar to the commercial CaF2:Tm. A linear dose response curve was obtained for the range 0.1 mGy to 100 Gy, with the onset of a supralinear behavior at 50 Gy up to 100 Gy. The minimum measurable dose for gamma was around 100 mu Gy for a 6.0 mm diameter by 1.0 mm in thickness pellet No significant fading was observed in 60 days of storage, within experimental uncertainties, showing that the main dosimetric peak is stable. (C) 2015 Elsevier Ltd. All rights reserved.
机译:氟化钙是已知的最古老的热致发光材料之一,被认为是最敏感的一种。这项工作提出了燃烧合成产生的CaF2:Tm的剂量学性质结果。 X射线衍射证实成功制备了CaF 2。使用Hammamatsu光谱仪获得的TL发射光谱具有相同的商品CaF2:Tm谱线,尽管跃迁P-3(0)-> F-3(4)(455 nm)和(1)G(4)- > H-3(6)(482 nm)被显示成比例地更强。使用了去卷积技术,发现了七个类似于商业CaF2:Tm的辉光峰。在0.1 mGy至100 Gy范围内获得了线性剂量反应曲线,并在50 Gy至100 Gy范围内出现了超线性行为。对于直径为6.0毫米乘厚度为1.0毫米的颗粒,γ的最小可测量剂量约为100μGy。在实验不确定性的条件下,储存60天未观察到明显的褪色,表明主要的剂量峰是稳定的。 (C)2015 Elsevier Ltd.保留所有权利。

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