首页> 外文期刊>Langmuir: The ACS Journal of Surfaces and Colloids >Capillary Forces between Colloidal Particles Confined in a Liquid Film: The Finite -Meniscus Problem
【24h】

Capillary Forces between Colloidal Particles Confined in a Liquid Film: The Finite -Meniscus Problem

机译:限制在液膜中的胶体颗粒之间的毛细作用力:有限-半月板问题

获取原文
获取原文并翻译 | 示例

摘要

We consider a system made of two spherical particles confined between two fluid interfaces. The concept is illustrated in experiments with polystyrene micrometer-sized particles located between the two membranes of a bilamellar giant lipid vesicle. The particles locally separated the membranes and form a "Plateau border", which is filled with water. Experiments based on optical manipulation and dynamometry readily show that the particles attract each other. The interaction force is long-ranged(several particle radii) and goes through a maximum(about a piconeton)at finite particle separation. We propose a theory of the interaction , based on the linearized Laplace equation for the meniscus profile. The theory predicts that the meniscus around an isolated particle is finite, that is, bounded by a peripheral contact line, outside of which the film surfaces are equidistant. When two particles come near each other, their menisci overlap and fuse to form a unique meniscus with a new peripheral line .This is the source of capillary interaction . The computation yields a characteristic nonmonotonic force-versus-distance profild , as experimentally observed with the latex particles. The computed profile quantitatively fits to the experimental data, with a single adjustable parameter, the bilayer tension. Other features of the interaction (hysteresis, dependence on particle size) are discussed. We find that the capillary attraction in general is strong enough to cause aggregation of the confined colloidal particles
机译:我们考虑由限制在两个流体界面之间的两个球形颗粒组成的系统。在实验中说明了这一概念,该实验是通过在一个巨大的小脂质囊泡的两个膜之间的聚苯乙烯微米级颗粒进行的。颗粒局部分离膜并形成充满水的“高原边界”。基于光学操作和测功的实验很容易地表明,颗粒相互吸引。相互作用力是远距离的(几个粒子半径),并且在有限的粒子分离时会经历一个最大值(约皮微微微)。我们基于弯月面轮廓的线性化拉普拉斯方程,提出了一种相互作用的理论。该理论预测,隔离颗粒周围的弯液面是有限的,即受外围接触线限制,外围接触线的膜表面等距。当两个粒子彼此靠近时,它们的弯液面重叠并融合在一起,形成具有新外围线的独特弯液面。这是毛细管相互作用的源头。计算产生了特征性的非单调力-距离-分布图,如对乳胶颗粒的实验观察到的。计算出的轮廓通过单个可调参数(双层张力)在数量上适合实验数据。讨论了相互作用的其他特征(磁滞,对粒度的依赖性)。我们发现,毛细管吸引力通常足够强,足以引起受限的胶体颗粒聚集

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号