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Acetone Gas-sensing Properties of Multiple-networked Pd-decorated Bi2O3 Nanorod Sensors

机译:多网络Pd装饰的Bi2O3纳米棒传感器的丙酮气敏特性

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摘要

This study examined the sensing properties of Bi2O3 nanorods decorated with Pd nanoparticles. Pd-decorated beta-Bi2O3 nanorods were prepared by immersing the Bi2O3 nanorods in ethanol/(50 mM)PdCl2 solution followed by UV irradiation and annealing. The Bi2O3 nanorods decorated with Pd nanoparticles showed faster and stronger response to acetone gas than the pristine Bi2O3 nanorods. Interestingly, the difference in response time between the Pd-decorated Bi2O3 nanorod sensor and pristine Bi2O3 nanorod sensor increased with increasing the acetone gas concentration. In contrast, the difference in recovery time between the two nanorod sensors decreased with increasing the acetone gas concentration. This difference can be explained using the chemical mechanism. The underlying mechanism for the enhanced response of the Bi2O3 nanorods decorated with Pd nanoparticles to acetone gas is also discussed.
机译:这项研究检查了装饰有Pd纳米粒子的Bi2O3纳米棒的传感特性。通过将Bi2O3纳米棒浸入乙醇/(50 mM)PdCl2溶液中,然后进行UV辐射和退火,来制备装饰Pd的β-Bi2O3纳米棒。与原始的Bi2O3纳米棒相比,装饰有Pd纳米颗粒的Bi2O3纳米棒对丙酮气体的响应更快,更强。有趣的是,装饰Pd的Bi2O3纳米棒传感器和原始的Bi2O3纳米棒传感器之间的响应时间差随着丙酮气体浓度的增加而增加。相反,两个纳米棒传感器之间的恢复时间差异随着丙酮气体浓度的增加而减小。可以使用化学机理解释这种差异。还讨论了用Pd纳米粒子修饰的Bi2O3纳米棒增强对丙酮气体的响应的潜在机理。

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