Convenient Synthesis of New Anionic Water-Soluble Phosphanes and Applications in Inter-and Intramolecular Heck Reactions

Remi Amengual; Emilie Genin; Veronique Michelet; Monique Savignac; Jean-Pierre Genet

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Convenient Synthesis of New Anionic Water-Soluble Phosphanes and Applications in Inter-and Intramolecular Heck Reactions

机译：新型阴离子水溶性膦的简便合成及其在分子间和分子内的Heck反应中的应用

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The vesatile preparation of new anionic water-soluble ligands derived from triphenylphosphane is described based on halogen-lithium exchange followed by CO_2 quenching. Efficient inter-and intramolecular Heck reactions have been disclosed. Comparison with other anionic and cationic ligands showed that meta substitution on the aromatic ring enhanced the reactivity.

机译：描述了基于卤素-锂交换然后CO 2猝灭的衍生自三苯基膦的新型阴离子水溶性配体的泡沫制备。已经公开了有效的分子间和分子内Heck反应。与其他阴离子和阳离子配体的比较表明，芳环上的间位取代增强了反应性。

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来源
《Advanced synthesis & catalysis》 |2002年第4期|共6页
作者
Remi Amengual; Emilie Genin; Veronique Michelet; Monique Savignac; Jean-Pierre Genet;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;化学反应过程;
关键词
carboxylated phosphane; heck reactions; homogeneous catalysis; palladium; water-soluble ligand;

机译：羧化膦;eck反应;均相催化;钯;水溶性配体;

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专利

1. Convenient Synthesis of New Anionic Water-Soluble Phosphanes and Applications in Inter-and Intramolecular Heck Reactions [J] . Remi Amengual, Emilie Genin, Veronique Michelet, Advanced synthesis & catalysis . 2002,第3a4期

机译：新型阴离子水溶性膦的简便合成及其在分子间和分子内的Heck反应中的应用
2. Application of 3,3 -disubstituted xylBINAP derivatives in inter-and intramolecular asymmetric Heck/Mizorold reactions [J] . Danica A. Rankic, Daniela Lucciola, Brian A. Keay Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第43期

机译：3,3-二取代的xylBINAP衍生物在分子间和分子内不对称Heck / Mizorold反应中的应用
3. Catalytic Asymmetric Synthesis of Quaternary Carbon Centers: Investigation of Intramolecular Heck Reactions and the Application to Calabar Alkaloid Synthesis [J] . Ulrich Iserloh, Dennis P. Curran Chemtracts . 1999,第4期

机译：季碳中心的催化不对称合成：分子内Heck反应的研究及其在卡拉巴尔生物碱合成中的应用
4. Catalytic Asymmetric Synthesis of Planar Chiral Arene Chromium Complex by Intramolecular Heck Reaction [C] . Ken Kamikawa, Kenji Harada, Junichi Yogo, Symposium on Organometallic Chemistry . 2004

机译：分子内静脉反应催化不对称合成平面手性芳烃铬复合物
5. An application of the intramolecular Heck reaction: A new strategy in the synthesis of Hasubanan alkaloids. Preparation of unsymmetrical biaryls via the Stille cross-coupling reaction: Synthesis of highly functional intermediates towards the synthesis of vindoline. [D] . Frank, Anthony Joseph. 2002

机译：分子内Heck反应的应用：合成Hasubanan生物碱的新策略。通过Stille交叉偶联反应制备不对称的联芳基：合成高功能性中间体，合成长春新碱。
6. Synthesis of pyrrolidinedione-fused hexahydropyrrolo21-aisoquinolines via three-component 3 + 2 cycloaddition followed by one-pot N-allylation and intramolecular Heck reactions [O] . Xiaoming Ma, Suzhi Meng, Xiaofeng Zhang, 2020

机译：通过三分组分3 + 2环加入合成吡咯烷二酮熔融六氢吡咯烷21-A异喹啉然后是单罐N-烯丙基化和分子内的静脉反应
7. Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions - model studies for the total synthesis of complex cardenolides [O] . Laschat, Sabine, Narjes, Frank, Overmann, Larry E. 2013

机译：分子内Heck反应在制备具有顺式a-B环融合的类固醇和萜中间体中的应用 - 复合型Cardenolides全合成的模型研究

Convenient Synthesis of New Anionic Water-Soluble Phosphanes and Applications in Inter-and Intramolecular Heck Reactions

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