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Catalytic Asymmetric Synthesis of Planar Chiral Arene Chromium Complex by Intramolecular Heck Reaction

机译：分子内静脉反应催化不对称合成平面手性芳烃铬复合物

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Asymmetric intramolecular Heck reaction of tricabonyl(2,6-dibutenylchlorobenzene)chromium in the presence of chiral phosphine-palladium catalyst gave the bicyclic chromium complex up to 73% ee.

机译：三丙二醇（2,6-二丁苯基氯苯）铬在手性膦 - 钯催化剂存在下的不对称分子内的反应使双环铬复合物高达73％EE。

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《Symposium on Organometallic Chemistry》|2004年||共2页
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Ken Kamikawa; Kenji Harada; Junichi Yogo; Motokazu Uemura;
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中图分类元素有机化合物;
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专利

1. Catalytic asymmetric induction of planar chirality: palladium catalyzed intramolecular Mizoroki-Heck reaction of prochiral (arene)chromium complexes [J] . Kamikawa K, Harada K, Uemura M Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2005,第8期

机译：平面手性的催化不对称诱导：钯催化前手性（芳烃）铬配合物的分子内Mizoroki-Heck反应
2. Gold(I)-catalyzed asymmetric induction of planar chirality by intramolecular nucleophilic addition to chromium-complexed alkynylarenes: Asymmetric synthesis of planar chiral (1H-isochromene and 1,2- dihydroisoquinoline)chromium complexes [J] . Murai M., Sota Y., Onohara Y., The Journal of Organic Chemistry . 2013,第21期

机译：金（I）催化的分子内亲核加成铬复杂的炔芳烃的平面手性的不对称诱导：平面手性（1H-异戊二烯和1,2-二氢异喹啉）铬配合物的不对称合成
3. Asymmetric synthesis of axially chiral benzamides and anilides utilizing planar chiral arene chromium complexes [J] . Koide H, Hata T, Yoshihara K, Tetrahedron . 2004,第20期

机译：利用平面手性芳烃铬配合物不对称合成轴向手性苯甲酰胺和苯胺
4. Catalytic Asymmetric Synthesis of Planar Chiral Arene Chromium Complex by Intramolecular Heck Reaction [C] . Ken Kamikawa, Kenji Harada, Junichi Yogo, Symposium on Organometallic Chemistry . 2004

机译：分子内静脉反应催化不对称合成平面手性芳烃铬复合物
5. Design and synthesis of novel chiral arsines for asymmetric Wittig reactions and palladium-catalyzed asymmetric allylic alkylation and asymmetric Heck reactions. [D] . Wu, Huafeng. 2004

机译：设计和合成用于不对称Wittig反应和钯催化的不对称烯丙基烷基化和不对称Heck反应的新型手性ral。
6. Tricarbonyl(η6-Arene)Chromium(0) Complexes as Chiral Auxiliaries: Asymmetric Synthesis of β-Lactones [O] . Paola Del Buttero, Deborah Montrasio 2001

机译：三羰基（η6-芳烃）铬（0）配合物作为手性助剂：β-内酯的不对称合成
7. Catalytic Asymmetric CH Arylation of (6Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines [O] . -1

机译：（6arene）铬配合物的催化不对称CH芳基化：容易进入平面手性膦

Catalytic Asymmetric Synthesis of Planar Chiral Arene Chromium Complex by Intramolecular Heck Reaction

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