Facile Approach to Graft Ionic Liquid into MOF for Improving the Efficiency of CO2 Chemical Fixation

摘要

This work describes a facile approach to modify metal-organic frameworks (MOFs) with ionic liquids (ILs), rendering them as useful heterogeneous catalysts for CO, chemical fixation. An amino-functionalized imidazolium-based ionic liquid is firmly grafted into the porous MOF, MIL-101 SO3H by the acid base attraction between positively charged ammonium groups on the IL and negatively charged sulfonate groups from the MOF. Analyses by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, H-1 NMR, and N-2 sorption experiments reveal the MOF-supported ionic liquid (denoted as IL a@ MOF) material remains intact while functioning as a recyclable heterogeneous catalyst that can efficiently convert CO2 and epichlorohydrin into chloropropene carbonate without the addition of a cocatalyst.