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Effect of post-deposition annealing on the properties of ZnO films obtained by high temperature, micro-controller based SILAR deposition

机译:沉积退火对高温,微控制器Sill沉积获得的ZnO膜性能的影响

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摘要

The ZnO thin films were prepared by successive ionic layer adsorption and reaction (SILAR) method at elevated precursor temperature. The films were later subjected to post-deposition annealing at different temperatures. This annealing process was found to be beneficial as it improved the structural and optical properties of the films. The ZnO films obtained by SILAR were found to be polycrystalline with hexagonal crystal structure. The crystallite size of the films increased considerably after annealing. The annealed films also showed very high absorption in UV region with marginal change in band gap. Both the crystallite size and optical absorbance were found to increase proportionately with the annealing temperature.
机译:通过升高前体温度下的连续离子层吸附和反应(Sill)方法制备ZnO薄膜。 后来将薄膜进行不同温度的沉积后退火。 发现这种退火过程有益,因为它改善了薄膜的结构和光学性质。 通过Sill获得的ZnO膜被发现是具有六边形晶体结构的多晶。 在退火后,薄膜的微晶尺寸会显着增加。 退火薄膜还显示出在UV区域中具有非常高的吸收,具有边缘变化的带隙。 发现微晶尺寸和光学吸光度均与退火温度相比成比例地增加。

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