Study of Kinetics and Mechanism of Heterogenous Catalytic Hydrazinolysis of Oleic Acid

Dzhumadullaeva S. A.; Baeshov A. B.

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Study of Kinetics and Mechanism of Heterogenous Catalytic Hydrazinolysis of Oleic Acid

机译：油酸异源催化水解的动力学和机理研究

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摘要

Kinetics and mechanism of the hydrazinolysis of oleic acid in the presence of a highly basic anionexchange resin AV-17-8 have been studied for the first time. The first reaction rate order has been found. The values of activation energy and entropy of the process have been determined. A plausible reaction mechanism involving a fixed resin cation has been proposed basing on the kinetic and IR spectroscopy data.

机译：第一次研究了油酸在高碱性的阴离子树脂AV-17-8存在下油酸的动力学和机制已经研究过。已经找到了第一种反应率顺序。已经确定了激活能量和过程的熵的值。已经提出了一种涉及固定树脂阳离子的可粘合反应机理，基于动力学和IR光谱数据。

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《Russian Journal of General Chemistry》 |2019年第2期|共4页
作者
Dzhumadullaeva S. A.; Baeshov A. B.;
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作者单位

Kh A Yassawi Int Kazakh Turkish Univ Pr B Sattarkhanova 29 Turkestan 161200 Kazakhstan;

Kh A Yassawi Int Kazakh Turkish Univ Pr B Sattarkhanova 29 Turkestan 161200 Kazakhstan;

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正文语种 eng
中图分类化学;
关键词
hydrazinolysis; oleic acid; anion-exchange resin; hydrazides;

机译：肼溶解;油酸;阴离子交换树脂;肼;

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6. Kinetic Analysis of Autotaxin Reveals Substrate-specific Catalytic Pathways and a Mechanism for Lysophosphatidic Acid Distribution [O] . Lauren P. Saunders, Wenxiang Cao, William C. Chang, 2011

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Study of Kinetics and Mechanism of Heterogenous Catalytic Hydrazinolysis of Oleic Acid

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