Synthesis of ruthenium-bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines

Kitano Takeo; Komuro Takashi; Sato Keita; Tobita Hiromi

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Synthesis of ruthenium-bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines

机译：通过双（烯丙基）钌（II）复合物与双（氢硅烷基）x吨和膦酸盐的反应合成钌 - 双（甲硅烷基）螯合络合物的螯合络合物

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来源
《Journal of Organometallic Chemistry》 |2020年第1期|共8页
作者
Kitano Takeo; Komuro Takashi; Sato Keita; Tobita Hiromi;
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作者单位

Tohoku Univ Grad Sch Sci Dept Chem Sendai Miyagi 9808578 Japan;

Tohoku Univ Grad Sch Sci Dept Chem Sendai Miyagi 9808578 Japan;

Tohoku Univ Grad Sch Sci Dept Chem Sendai Miyagi 9808578 Japan;

Tohoku Univ Grad Sch Sci Dept Chem Sendai Miyagi 9808578 Japan;

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正文语种 eng
中图分类元素有机化合物;
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1. Synthesis of ruthenium-bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines [J] . Kitano Takeo, Komuro Takashi, Sato Keita, Journal of Organometallic Chemistry . 2020,第1期

机译：通过双（烯丙基）钌（II）复合物与双（氢硅烷基）x吨和膦酸盐的反应合成钌 - 双（甲硅烷基）螯合络合物的螯合络合物
2. Synthesis of metallacarborane ruthenium(II) and ruthenium(III) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions [J] . Grishin I. D., Agafonova K. S., Kostyukovich A. Yu., Russian Chemical Bulletin . 2016,第6期

机译：螯合1,3-双（二苯基膦基）丙烷配体的金属碳硼烷钌（II）和钌（III）配合物的合成及其在单电子氧化还原反应中的相互转化
3. Synthesis of metallacarborane ruthenium(II) and ruthenium(III) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions [J] . Grishin I. D., Agafonova K. S., Kostyukovich A. Yu., Russian Chemical Bulletin . 2016,第6期

机译：用螯合物1,3-双（二苯基膦基）丙烷配体合成金属酰胺钌（II）和钌（III）配合物及其在单电子氧化还原反应中的相互转化
4. Synthesis and Activity in Ring-Closing Metathesis of Phosphine and NHC-Containing Ruthenium–Indenylidene (Bis)Pyridine Complexes [C] . Herve Clavier, Steven P. Nolan NATO Advanced Study Institute on Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials . 2007

机译：膦酸环和含NHC钌 - 茚基（双）吡啶配合物的闭环复分解中的合成与活性
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Synthesis of Chromium(II) Complexes with Chelating Bis(alkoxide) Ligand and Their Reactions with Organoazides and Diazoalkanes [O] . Sudheer S. Kurup, Richard J. Staples, Richard L. Lord, 2020

机译：螯合双（烷氧基）配体的铬（II）配合物的合成及其与有机叠氮化物和重氮烷的反应
7. Synthesis, characterization, and reactivity of ruthenium bis-allyl complexes with chiral phosphine-phosphite ligands [O] . Vaquero Mónica, Vargas Rodríguez Sergio, Suárez Andrés, 2014

机译：钌-双烯丙基配合物与手性膦-亚磷酸酯配体的合成，表征和反应性
8. Dialkylamino Phosphorus Metal Carbonyls. 2. Bis(diisopropylamino)phosphido and (Diisopropylamino)phosphinidene Metal Carbonyl Complexes from Reactions of Manganese and Cobalt Carbonyls with Bis(diisopropylamino)phosphine [R] . King, R. B., Fu, W. K., Holt, E. M. 1986

机译：二烷基氨基磷酸金属羰基化合物。 2.来自锰和羰基钴与双（二异丙基氨基）膦的反应的双（二异丙基氨基）膦基和（二异丙基氨基）亚膦基金属羰基配合物

Synthesis of ruthenium-bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines

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