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Comprehensive study of hydrothermally grown ZnO nanowires

机译:水热生长ZnO纳米线的综合研究

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摘要

A hydrothermal procedure has been implemented to grow single-crystal ZnO nanowires (NWs) on sol-gel deposited seed layers. The main characteristics (diameter, length, and aspect ratio) of derived NWs have been studied by scanning electron microscopy in relation to morphological and structural properties of the ZnO films (mean grain size, surface coverage rate, and texture coefficient) and growth process parameters (growth duration and multi-growth procedure). It is shown how suitable combinations arising from the influence of the seed layer properties, growths of various durations, and implementation of a multi-growth process enable to finely tune the NW characteristics in a large range of values, i.e., a diameter, length, and aspect ratio varying in the 30-225 nm, 1.0-9.0 A mu m, and 30-50 ranges, respectively. On the basis of investigated experimental conditions, a simple model is developed that suitably describes the NW crystal growth as a function of the seed layer properties and growth duration. According to this model, lateral and longitudinal growth rates of around 0.01 nm/min and 25-30 nm/min, respectively, are extracted from experimental data and a minimal NW diameter of around 20 nm is predicted.
机译:已实施水热程序以在溶胶-凝胶沉积的种子层上生长单晶ZnO纳米线(NW)。通过扫描电子显微镜研究了与ZnO薄膜的形态和结构特性(平均晶粒尺寸,表面覆盖率和织构系数)以及生长工艺参数有关的衍生NW的主要特性(直径,长度和长宽比)。 (生长持续时间和多重生长过程)。它显示了种子层特性,各种持续时间的增长以及多重生长过程的实施所产生的合适组合如何使NW特性在较大的值范围(例如直径,长度,和长宽比分别在30-225 nm,1.0-9.0 Aμm和30-50范围内变化。在研究的实验条件的基础上,开发了一个简单的模型,该模型适当地描述了NW晶体的生长与晶种特性和生长持续时间的关系。根据该模型,从实验数据中分别提取了约0.01 nm / min和25-30 nm / min的横向和纵向生长速率,并预测了约20 nm的最小NW直径。

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