Cloud point extraction coupled with microwave or ultrasonic assisted back extraction as a preconcentration step prior to gas chromatography

摘要

Cloud point extraction of nonionic and anionic surfactants was applied as a preconcentration step prior to gas chromatography. No cleanup step preceded chromatographic analysis. The obtained surfactant-rich phase was treated with water-immiscible solvents, and the target analytes were back extracted by short-term microwave application or ultrasonication. A mixture of six PAHs (naphthalene, acenaphthene, fluorene, anthracene, fluoranthene, pyrene) was used as test compounds. The obtained detection limits were in the microgram per liter area. Recoveries of spiked water and soil samples ranged between 92 and 105% while analysis of certified reference materials gave results in good agreement with the certified values. Under the optimum experimental conditions, there was no interference or blocking of the column. According to our results, this approach presents a convenient solution to the up-to-date problem of combining gas chromatography with micellar cloud point extraction.