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Challenge on analysis of individual diesel exhaust hydrocarbons

机译:单个柴油机废气碳氢化合物分析面临的挑战

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摘要

A method of analyzing individual hydrocarbons in diesel exhaust gas was developed in this study. In this method, diesel exhaust after through the heated stainless steel tube, was tried to directly concentrate in capillary column at 0 to 5 ℃ in gas chromatograph. In this result, several handred hydrocarbons with a carbon number of 8 to 21 made sharp peaks on the chromatogram. In the lower load condition of engine, the pattern of hydrocarbons on the chromatogram was similar to diesel fuel hydrocarbons, and the number of thermal decomposition conponents were few. When higher load condition of engine, the pattern of hydrocarbons were not similar to diesel fuel hydrocarbons and there were many thermal decomposition conponents.
机译:本研究开发了一种分析柴油机废气中单个碳氢化合物的方法。用这种方法,尝试将柴油废气通过加热的不锈钢管后,在气相色谱仪中直接浓缩在0至5℃的毛细管柱中。结果,几种碳原子数为8至21的人工碳氢化合物在色谱图中形成了尖锐的峰。在发动机低负荷工况下,色谱图上的碳氢化合物模式与柴油燃料碳氢化合物相似,且热分解组分的数量很少。当发动机较高负荷工况时,碳氢化合物的形态与柴油燃料碳氢化合物不相似,并且存在大量的热分解成分。

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