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Effects of different substrate on the structural and optical properties of atomic layer deposited TiO2 thin films

机译:不同衬底对原子层沉积TiO2薄膜结构和光学性能的影响

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摘要

In this work, Titanium dioxide (TiO2) thin films were prepared by atomic layer deposition (ALD). The effect of different substrates on the structural and optical properties of TiO2 thin films was studied. The prepared films were characterized by X - Ray diffraction (XRD) method, reflectance spectroscopy, Photoluminescence (PL) spectroscopy, Field Effect Scanning Electron Microscopy (FESEM) and Energy Dispersive X - Ray (EDX). The XRD results show that the anatase and rutile mixed crystalline TiO2 structure for each substrate. The stoichiometric ratio of the film was confirmed by EDX analysis. The room temperature PL spectra of TiO2 thin films show the band gap and defect peak at 409 nm and 420 nm with excitation at 325 nm. The surface morphology shows that TiO2 on FTO have high roughness as compared to others with irregular particles.
机译:在这项工作中,通过原子层沉积(ALD)制备了二氧化钛(TiO2)薄膜。研究了不同基材对TiO2薄膜结构和光学性能的影响。通过X射线衍射(XRD)法,反射光谱,光致发光(PL)光谱,场效应扫描电子显微镜(FESEM)和能量色散X射线(EDX)对制备的膜进行表征。 XRD结果表明,每种底物均具有锐钛矿型和金红石型混合晶体TiO2。通过EDX分析确认了膜的化学计量比。 TiO2薄膜的室温PL光谱在325 nm激发下在409 nm和420 nm处显示带隙和缺陷峰。表面形态表明,与其他不规则颗粒相比,FTO上的TiO2具有较高的粗糙度。

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