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首页> 外文期刊>Journal of Materials Chemistry, B. materials for biology and medicine >Fabrication and adhesion of a bio-inspired microarray: capillarity-induced casting using porous silicon mold
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Fabrication and adhesion of a bio-inspired microarray: capillarity-induced casting using porous silicon mold

机译:受生物启发的微阵列的制备和粘附:使用多孔硅模具的毛细作用诱导浇铸

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摘要

Inspired by the setal microstructure found on the gecko's toe-pads, a highly dense array of high-aspect-ratio (HAR) artificial setae has been developed with a novel moid-casting technique using a porous silicon (PSi) template. To overcome the high fluid resistance in the HAR capillary pores, the PSi template surface is modified with a monolayer coating of dimethylsilane. The coating exhibits similar chemical composition and surface energy to the precursor of the poly(dimethylsiloxane) (PDMS) replica. The compatibility between the template and the replica addresses the major challenge of molding HAR microstructures, resulting in high-resolution replicas of artificial PDMS microsetae with complicated geometry resembling a real gecko's setae. The artificial setae are characterized by a mean radius of 1.3 μm, an aspect ratio of 35.1, and a density of ~4.7 × 10~5 per mm~2. Results from adhesion characterizations reveal that with increasing preload, the shear adhesion of micro-setae continually increases while the normal adhesion decreases. The unique adhesion performance is caused by both van der Waals forces and the elastic resistance of PDMS setae. With further structural optimizations and the addition of an actuation mechanism, artificial setal arrays might eventually demonstrate the fascinating adhesion performances of the gecko for mimetic devices such as wall-climbing devices.
机译:受壁虎脚趾垫上的牙结石微观结构的启发,已经开发出了一种高密度的高纵横比(HAR)人工刚毛阵列,它使用多孔硅(PSi)模板通过新颖的铸模技术进行开发。为了克服HAR毛细孔中的高流体阻力,PSi模板表面用二甲基硅烷的单层涂层改性。该涂层表现出与聚(二甲基硅氧烷)(PDMS)复制品的前体相似的化学组成和表面能。模板和复制品之间的兼容性解决了模制HAR微结构的主要挑战,从而导致了人工PDMS微型定植体的高分辨率复制品,其复杂的几何形状类似于真实的壁虎的定植体。人造刚毛的特征在于平均半径为1.3μm,纵横比为35.1,密度为〜4.7×10〜5 / mm〜2。粘附特性的结果表明,随着预紧力的增加,微刚毛的剪切粘附力持续增加,而正常粘附力则下降。独特的粘合性能是由范德华力和PDMS刚毛的弹性阻力共同引起的。通过进一步的结构优化和附加的致动机制,人造setset阵列可能最终展示出壁虎对于模仿设备(例如爬壁设备)的迷人附着性能。

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