Synthesis of aryl (~(35)S)sulfones: Friedel-CrNts sulfonylation of aryl ethers with high specific activity (~(35)S)methanesulfonyl chloride

MICHAEL A. WALLACE; CONRAD RAAB; DENNIS DEAN; DAVID MELILLO

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Synthesis of aryl (~(35)S)sulfones: Friedel-CrNts sulfonylation of aryl ethers with high specific activity (~(35)S)methanesulfonyl chloride

机译：芳基（〜（35）S）砜的合成：具有高比活度（〜（35）S）甲磺酰氯的芳基醚的Friedel-CrNts磺酰化

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Lewis acid-assisted sulfonylation of anisole with [~(35)S]methanesulfonyl chloride Nforded high specific activity aryl [~(35)S]sulfones. Demethylation and treatment with triflic anhydride gave the versatile [~(35)S]triflate 1 in good overall yields. The [~(35)S]sulfone triflate could be further functionalized by catalyzed aminations, Stille couplings, and cyanation.

机译：路易斯酸辅助苯甲醚与[〜（35）S]甲磺酰氯的磺酰化Nforded高比活芳基[〜（35）S]砜。脱甲基并用三氟甲磺酸酐处理得到通用的[〜（35）S]三氟甲磺酸盐1，总收率良好。 [〜（35）S]砜三氟甲磺酸酯可通过催化胺化，斯蒂勒偶联和氰化进一步官能化。

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来源
《Journal of Labelled Compounds and Radiopharmaceuticals》 |2007年第6期|共3页
作者
MICHAEL A. WALLACE; CONRAD RAAB; DENNIS DEAN; DAVID MELILLO;
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正文语种 eng
中图分类药学;
关键词
~(35)Smethanesulfonyl chloride; aryl ~(35)Ssulfones; ~(35)Ssulfone triflate;

机译：[〜（35）S]甲磺酰氯;芳基[〜（35）S]砜;[〜（35）S]三氟甲磺酸砜;

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1. Synthesis of aryl (~(35)S)sulfones: Friedel-CrNts sulfonylation of aryl ethers with high specific activity (~(35)S)methanesulfonyl chloride [J] . MICHAEL A. WALLACE, CONRAD RAAB, DENNIS DEAN, Journal of Labelled Compounds and Radiopharmaceuticals . 2007,第5a6期

机译：芳基（〜（35）S）砜的合成：具有高比活度（〜（35）S）甲磺酰氯的芳基醚的Friedel-CrNts磺酰化
2. Exploring a methylsulfination approach to high specific activity aryl methyl (~(35)S)sulfones [J] . Coelho R.V.Jr, Schildknegt, K. Journal of Labelled Compounds and Radiopharmaceuticals . 2010,第5a6期

机译：探索高比活性芳基甲基（〜（35）S）砜的甲基硫化方法
3. Exploring a methylsulfination approach to high specific activity aryl methyl (~(35)S)sulfones [J] . Coelho R.V.Jr, Schildknegt, K. Journal of Labelled Compounds and Radiopharmaceuticals . 2010,第5a6期

机译：探索高比活性芳基甲基（〜（35）S）砜的甲基硫化方法
4. Synthesis and characterization of novel poly (aryl ether sulfone ketone) s containing m-sulfonylhenzonyi linkage in the main chains [C] . Feng Ding, Dazhi Wang, Shaoyin Zhang International Conference on Chemical, Material and Metallurgical Engineering . 2012

机译：主链中含有M-磺酰基团延迟的新型聚（芳基醚砜酮）丝的合成与表征
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8. Chemical Modification of Matrix Resin Networks with Engineering Thermoplastics. III. Synthesis and Properties of Epoxy Networks Modified with Amine Terminated Poly(Aryl Ether Sulfone) Oligomers [R] . Hedrick, J. L., Jurek, M. J., Yilgor, I., 1985

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Synthesis of aryl (~(35)S)sulfones: Friedel-CrNts sulfonylation of aryl ethers with high specific activity (~(35)S)methanesulfonyl chloride

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