Synthesis of Functionalized Isoquinolines via Sequential Cyclization/Cross-Coupling Reactions

Xingxin Yu; Jie Wu

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Synthesis of Functionalized Isoquinolines via Sequential Cyclization/Cross-Coupling Reactions

机译：通过顺序环化/交叉偶联反应合成功能化异喹啉

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CuX2-mediated cyclization of 2-alkynylbenzaldehyde O-methyl oximes in N,N-dimethylacetamide (DMA) gave rise to 4-chloroisoquinolines in good yield, which underwent the palladium-catalyzed cross-coupling reactions of arylboronic acids subsequently to afford the functionalized isoquinolines.

机译：CuX2介导的N，N-二甲基乙酰胺（DMA）中的2-炔基苯甲醛O-甲基肟的环化反应生成高产率的4-氯异喹啉，随后进行了钯催化的芳基硼酸的交叉偶联反应，从而得到官能化的异喹啉。

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《Journal of combinatorial chemistry》 |2009年第5期|共5页
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Xingxin Yu; Jie Wu;
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正文语种 eng
中图分类化学;
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1. Synthesis of Functionalized Isoquinolines via Sequential Cyclization/Cross-Coupling Reactions [J] . Xingxin Yu, Jie Wu Journal of combinatorial chemistry . 2009,第5期

机译：通过顺序环化/交叉偶联反应合成功能化异喹啉
2. Synthesis of functionalized H-pyrazolo[5,1-a]isoquinolines via sequential reactions of N'-(2-alkynylbenzylidene)hydrazides [J] . Zhiyuan Chen, Mingchao Su, Xingxin Yu, Organic & biomolecular chemistry . 2009,第22期

机译：N'-（2-炔基亚苄基）酰肼的顺序反应合成功能化H-吡唑并[5,1-a]异喹啉
3. Cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents and their application to the synthesis of 1,3-diols [J] . Hidenori Someya, Hirohisa Ohmiya, Hideki Yorimitsu, Tetrahedron . 2007,第35期

机译：6-卤-1-己烯衍生物与格氏试剂的钴催化连续环化/交叉偶联反应及其在1,3-二醇合成中的应用
4. Aqueous Phase Sonogashira Cross-Coupling Reaction in Synthesis of Bile Acid Conjugates of Purine and Pyrimidine Nucleosides and Nucleoside Triphosphates; Towards Bile Acid -Functionalized Nucleic Acids [C] . Satu Ikonen, Radek Pohl, Michal Hocek European Symposium on Organic Chemistry . 2009

机译：水相Sonogashira交叉偶联反应在嘌呤和嘧啶核苷的合成中合成，嘧啶核苷和核苷三磷酸盐;朝向胆汁酸 - 官能化核酸
5. An application of the intramolecular Heck reaction: A new strategy in the synthesis of Hasubanan alkaloids. Preparation of unsymmetrical biaryls via the Stille cross-coupling reaction: Synthesis of highly functional intermediates towards the synthesis of vindoline. [D] . Frank, Anthony Joseph. 2002

机译：分子内Heck反应的应用：合成Hasubanan生物碱的新策略。通过Stille交叉偶联反应制备不对称的联芳基：合成高功能性中间体，合成长春新碱。
6. Sequential and iterative Pd-catalyzed cross-coupling reactions in organic synthesis [O] . Patrick Dobrounig, Melanie Trobe, Rolf Breinbauer -1

机译：有机合成中顺序和迭代的Pd催化的交叉偶联反应
7. Cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents and their application to the synthesis of 1,3-diols [O] . Someya Hidenori, Ohmiya Hirohisa, Yorimits Hideki, 2007

机译：6-卤-1-己烯衍生物与格氏试剂的钴催化连续环化/交叉偶联反应及其在1,3-二醇合成中的应用

Synthesis of Functionalized Isoquinolines via Sequential Cyclization/Cross-Coupling Reactions

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