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Dynamic-Mechanical study of water-blown rigid polyurethane foams with and without soy flour

机译:有和没有大豆粉的水硬硬质聚氨酯泡沫的动态力学研究

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摘要

Glass transition temperatures of water-blown rigid polyurethane foams at three levels of initial water content, 4.5-5.5%, and five levels of soy flour, 0-40%, were determined by dynamic-mechanical instrumentation at the temperature range of 50- 280degC and the frequencies from 0.1 to 20 Hz. The results showed that both the addition of soy flour in the rigid polyurethane foam system and increasing initial water content contributed to a higher glass transition temperature. Moreover, increasing the percentage of the soy flour in the rigid polyurethane foam system led to higher compressive strength and broader master curves for the imaginary part of the elastic modulus. The KWW function fitted the master curve better than the HN and CD functions.
机译:通过动态机械仪器在50- 280degC的温度范围内测定了三种初始水含量为4.5-5.5%的水发泡硬质聚氨酯泡沫的玻璃化转变温度,以及0-40%的五种大豆粉的玻璃化温度。频率从0.1到20 Hz。结果表明,在硬质聚氨酯泡沫体系中添加大豆粉和增加初始水含量都有助于提高玻璃化转变温度。此外,增加硬质聚氨酯泡沫体系中大豆粉的百分比会导致较高的抗压强度和弹性模量虚部的更宽的主曲线。 KWW功能比HN和CD功能更适合主曲线。

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