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Enhanced Multiple Path Lines in Magnetic EXAFS

机译:磁性EXAFS中的增强多路径线

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In systematic magnetic EXAFS studies it is observed that in the Fourier transform (FT) of the dichroic signal multiple path peaks are strongly enhanced, while the corresponding maxima at higher r-values in the spin-averaged EXAFS FT are much smaller or invisible. This behavior is reflected by the occurrence of additional harmonic frequencies in the magnetic raw spectra and explains their sharper structure. These observations can be interpreted by the different strengths of the elastic scattering cross sections for parallel and anti-parallel orientation of the outgoing photo-electron wave and the spins of the magnetic electrons. This phenomenon might also play an important role in the near edge dichroism of oxides, which show characteristic oscillations superimposed on the dichroic effect.
机译:在系统的磁性EXAFS研究中,观察到在二向色性信号的傅立叶变换(FT)中,多个路径峰得到了显着增强,而自旋平均EXAFS FT中在较高r值处的相应最大值小得多或不可见。磁性原始频谱中额外谐波频率的出现反映了这种行为,并解释了其更清晰的结构。这些观察结果可以通过弹性散射截面的不同强度来解释,这些弹性散射横截面对于出射光电子波和磁性电子自旋的平行和反平行取向。这种现象在氧化物的近边缘二向色性中也可能起重要作用,氧化物的边缘二向色性表现出叠加在二向色性效应上的特征振荡。

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