Flash photolysis and stopped flow studies of the 2'-methoxyflavylium network in aq. acidic and alkaline solution

摘要

The rate and equilibrium constants of the network of chemical species involving the dye 2'-rhethoxy-flavylium tetrafluoroborate were characterized using stopped flow and flash photolysis in both acidic and alkaline aqueous solution. The trans-chalcone is the thermodynamic stable species in acidic solutions 2 < pH < 7; irradiation of trans-chalcone at low pH leads to the corresponding coloured flavylium cation. The system reverts to its initial state in a few hours, in the dark. The kinetics of the various steps in the system were determined; flash photolysis revealed that the rate determining process of flavylium formation is the ring closure to give the corresponding hemiketal. In alkaline medium the ionized trans-chalcone is the stable form and clear evidence for the existence of a hemiketal species was obtained. A write-read-erase cycle can be performed with this compound.