In situ hydrothermal synthesis of dysprosium(iii) single-molecule magnet with lanthanide salt as catalyst

Liang L.; Peng G.; Li G.; Lan Y.; Powell A.K.; Deng H.

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In situ hydrothermal synthesis of dysprosium(iii) single-molecule magnet with lanthanide salt as catalyst

机译：以镧系元素盐为催化剂原位水热合成（iii）单分子磁体

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A family of six dinuclear lanthanide complexes have been obtained via in situ hydrothermal synthesis with lanthanide ions as catalyst. These six complexes are formulated as [Ln _2(3-Htzba) _2(3-tzba) _2(H _2O) _8]·4H _2O [Ln = Gd, 1; Dy, 2; Eu, 3; Tb, 4; Sm, 5; Er, 6; 3-H 2tzba = 3-(1H-tetrazol-5-yl) benzoic acid]. The magnetic investigations show that complex 2 behaves as a single-molecule magnet (SMM) with a quantum relaxation time of ～10 ~(-2) s

机译：通过以镧系离子作为催化剂的原位水热合成获得了六种双核镧系配合物。将这六个络合物配制成[Ln _2（3-Htzba）_2（3-tzba）_2（H _2O）_8]·4H _2O [Ln = Gd，1; Dy，2; Eu，3; Tb，4; Sm，5; 6 3-H 2tzba ＝ 3-（1H-四唑-5-基）苯甲酸]。磁性研究表明，配合物2表现为单分子磁体（SMM），量子弛豫时间为〜10〜（-2）s

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第19期|共8页
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Liang L.; Peng G.; Li G.; Lan Y.; Powell A.K.; Deng H.;
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1. In situ hydrothermal synthesis of dysprosium(iii) single-molecule magnet with lanthanide salt as catalyst [J] . Liang L., Peng G., Li G., Dalton transactions: An international journal of inorganic chemistry . 2012,第19期

机译：以镧系元素盐为催化剂原位水热合成（iii）单分子磁体
2. Synthesis, Structure, Magnetic and Photoluminescent Properties of Dysprosium(III) Schiff Base Single-Molecule Magnets: Investigation of the Relaxation of the Magnetization [J] . Long Jerome, Basalov Ivan V., Lyssenko Konstantin A., Chemistry, an Asian journal . 2020,第17期

机译：镝（III）Schiff基底单分子磁铁的合成，结构，磁性和光致发光性能：对磁化的松弛的研究
3. Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior [J] . Xu JX, Ma Y, Liao DZ, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第18期

机译：四个新的镧系元素-一氧化氮亚硝酸盐（Ln（III）= Pr-III，Sm-III，Eu-III，Tm-III）配合物和Tb-III配合物表现出单分子磁体行为
4. The local magnetic properties of Mn_6~(III) Cr~(III)~(3+) and Fe_6~(III) Cr~(III)~(3+) single-molecule magnets deposited on surfaces studied by spin-polarized photoemission and XMCD with circularly polarized synchrotron radiation [C] . U. Heinzmann, A. Helmstedt, N. Dohmeier, ICPEAC . 2014

机译：Mn_6〜（III）Cr〜（III）〜（3+）和Fe_6〜（III）Cr〜（III）〜（3+）单分子磁铁的局部磁性特性沉积在旋转的表面上 - 具有圆极化同步辐射的循环光曝光和XMCD
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling [O] . Thomas Pugh, Nicholas F. Chilton, Richard A. Layfield 2017

机译：连接锑的单分子磁体作为锑烷脱氢偶联的催化剂
7. Direct measurement of dysprosium(III)˙˙˙dysprosium(III) interactions in a single-molecule magnet [O] . Moreno Pineda, Eufemio, Chilton, Nicholas F, Marx, Raphael, 2014

机译：直接测量单分子磁体中的镝（III）˙˙dysprosium（III）相互作用

In situ hydrothermal synthesis of dysprosium(iii) single-molecule magnet with lanthanide salt as catalyst

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