Synthesis, Structure, Magnetic and Photoluminescent Properties of Dysprosium(III) Schiff Base Single-Molecule Magnets: Investigation of the Relaxation of the Magnetization

摘要

We report here the synthesis, structure, magnetic and photoluminescent properties of three new bifunctional Schiff-base complexes [Dy(L-1)(2)(py)(2)][B(Ph)(4)].py (1), [Dy(L-1)(2)Cl(DME)] . 0.5DME (2) and [Dy(L-2)(2)Cl] . 2.5(C7H8) (3) (HL1=Phenol, 2,4-bis(1,1-dimethylethyl)-6-[[(2-methoxy-5-methylphenyl)imino]methyl]; HL2=Phenol, 2,4-bis(1,1-dimethylethyl)-6-[[(2-methoxyphenyl)imino]methyl]). The coordination environment of the Dy(3+)ion and the direction of the anisotropic axis may be controlled by the combination of the substituent groups of the Schiff bases, the nature of the counter-ions (Cl(-)vs. BPh4-) and the coordinative solvent molecules. A zero-field slow relaxation of the magnetization is evidenced for all complexes but strong differences in the relaxation dynamics are observed depending on the Dy(3+)site geometry. In this sense, complex1exhibits an anisotropy barrier of 472 cm(,)(-1)which may be favourably compared to other related examples due to the shortening of the Dy-O bond in the axial direction. Besides, the three complexes exhibit a ligand-based luminescence making them as bifunctional magneto-luminescent systems.