A CONVENIENT PROCEDURE FOR THE REDUCTION OF S-(+)-SILYL SERINE METHYL ESTER TO CHIRAL SERINOL DERIVATIVES

Novachek KA.; Meyers AI.

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A CONVENIENT PROCEDURE FOR THE REDUCTION OF S-(+)-SILYL SERINE METHYL ESTER TO CHIRAL SERINOL DERIVATIVES

机译：S-（+）-甲硅烷基丝氨酸甲酯还原为手性三联醇衍生物的简便方法

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The reduction of S-(+)-serine methyl ester silyl ether with NaBH4 followed by acidic workup produced the chiral serinol derivatives with minimum racemization. Addition of MeMgBr gave the functionalized amine diol in high yield with no racemization. [References: 24]

机译：用NaBH4还原S-（+）-丝氨酸甲酯甲硅烷基醚，然后进行酸性后处理，生成的外消旋化程度最低的手性丝氨醇衍生物。 MeMgBr的添加以高收率得到了功能化的胺二醇，而没有外消旋作用。 [参考：24]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1996年第11期|共4页
作者
Novachek KA.; Meyers AI.;
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正文语种 eng
中图分类有机化学;
关键词
Amino-acids;

机译：氨基酸;

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1. A CONVENIENT PROCEDURE FOR THE REDUCTION OF S-(+)-SILYL SERINE METHYL ESTER TO CHIRAL SERINOL DERIVATIVES [J] . Novachek KA., Meyers AI. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第11期

机译：S-（+）-甲硅烷基丝氨酸甲酯还原为手性三联醇衍生物的简便方法
2. HIGHLY DIASTEREOSELECTIVE ADDITION OF SILYL ENOLATES TO CHIRAL IMINES DERIVED FROM (S)-VALINE METHYL ESTER USING LANTHANIDE TRIFLATE [J] . Cozzi PG., Umanironchi A., Disimone B. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第10期

机译：使用镧系元素三氟甲基磺酸酯对（S）-缬氨酸甲基酯衍生的手性烯丙基硅烷酯进行非对映选择性加成
3. Chiral Discrimination Effects in Langmuir Monolayers: Monolayers of Palmitoyl Aspartic Acid, N-Stearoyl Serine Methyl Ester, and N-Tetradecyl-γ,δ-dihydroxypentanoic Acid Amide [J] . N. Nandi, D. Vollhardt The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2003,第15期

机译：Langmuir单层的手性识别作用：棕榈酰天冬氨酸，N-硬脂酰丝氨酸丝氨酸甲酯和N-十四烷基-γ，δ-二羟基戊酸酰胺的单层
4. A Convenient Procedure for the Preparation of Levoglucosenone and Its Conversion to Novel Chiral Derivatives [C] . Walter S. Trahanovsky, Jason M. Ochaoda, Chen Wang, American Chemical Society . 2003

机译：制备左葡葡萄酒的方便步骤及其对新型手性衍生物的转化
5. Aspects of convenient synthesis of 2,2'-biimidazole derivatives and aliphatic poly(amino-ester)s. [D] . He, Feng. 2002

机译：方便合成2,2'-联咪唑衍生物和脂族聚（氨基酯）的方面。
6. Convenient Synthesis and Biological Evaluation of Modafinil Derivatives: Benzhydrylsulfanyl and Benzhydrylsulfinyl 123triazol-4-yl-methyl Esters [O] . Jae-Chul Jung, Yeonju Lee, Jee-Young Son, 2011

机译：莫达非尼衍生物的简便合成及生物学评价：苯甲基硫烷基和苯甲基亚磺酰基123三唑-4-基甲基酯
7. Convenient Synthesis and Biological Evaluation of Modafinil Derivatives: Benzhydrylsulfanyl and Benzhydrylsulfinyl [1,2,3]triazol-4-yl-methyl Esters [O] . Seikwan Oh, Mankil Jung, Eunyoung Lim, 2011

机译：莫达非尼衍生物的简便合成和生物学评价：二苯甲基硫烷基和二苯甲基亚磺酰基[1,2,3]三唑-4-基 - 甲基酯
8. Chiral Synthesis via Organoboranes. 33. The Controlled Reaction of B-Alkydiisopinocampheylboranes with Aldehydes Providing a Convenient Procedure for the Enantiomeric Enrichment of the Boronic Ester Products Through Kinetic Resolution [R] . Joshi, N. N., Pyun, C., Mahindroo, V. K., 1991

机译：有机硼烷的手性合成。 33.B-烷基异哌啶基硼烷与醛的可控反应通过动力学拆分提供了对硼酸酯产物对映体富集的方便程序

A CONVENIENT PROCEDURE FOR THE REDUCTION OF S-(+)-SILYL SERINE METHYL ESTER TO CHIRAL SERINOL DERIVATIVES

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