Palladium-catalyzed cyanoesterification of norbornenes with cyanoformates via the NC-Pd-COOR (R = Me and Et) intermediate

Nishihara Y; Inoue Y; Itazaki M; Takagi K

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Palladium-catalyzed cyanoesterification of norbornenes with cyanoformates via the NC-Pd-COOR (R = Me and Et) intermediate

机译：经由NC-Pd-COOR（R = Me和Et）中间体的钯催化的降冰片烯与氰基甲酸酯的氰基酯化

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摘要

Palladium-catalyzed cyanoesterification of norbornenes proceeds stereoselectively via NC-Pd-COOR (R = Me and Et) complexes as intermediates.

机译：降冰片烯的钯催化氰基酯化反应通过中间体NC-Pd-COOR（R = Me和Et）进行立体选择。

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来源
《Organic letters》 |2005年第13期|p. 2639-2641|共3页
作者
Nishihara Y; Inoue Y; Itazaki M; Takagi K;
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作者单位

Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan;

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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
CRYSTAL-STRUCTURES; ACHIRAL ADDITIVES; ALKYNES; COMPLEXES; TRANSITION; CYANIDE; CHLOROFORMATE; REACTIVITY; MECHANISM; ESTERS;

机译：晶体结构;非手性添加剂;炔烃;化合物;转变;氰化物;氯甲酸酯;反应性;机理;酯;

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专利

1. Palladium-catalyzed cyanoesterification of norbornenes with cyanoformates via the NC-Pd-COOR (R = Me and Et) intermediate [J] . Nishihara Y, Inoue Y, Itazaki M, Organic letters . 2005,第13期

机译：经由NC-Pd-COOR（R = Me和Et）中间体的钯催化的降冰片烯与氰基甲酸酯的氰基酯化
2. Preparation, Structures, and Thermal Reactivity of Alkoxycarbonyl(cyano)palladium(II) Complexes trans-Pd(COOR)(CN)(PPh_3)_2 (R = Me, Et, ~nPr, ~iPr, ~nBu, ~tBu, and Bn) as Intermediates of the Palladium-Catalyzed Cyanoesterification of Norbornene Der [J] . Yasushi Nishihara, Mitsuru Miyasaka, Yoshiaki Inoue Organometallics . 2007,第16期

机译：烷氧基羰基（氰基）钯（II）配合物反式-Pd（COOR）（CN）（PPh_3）_2（R = Me，Et，〜nPr，〜iPr，〜nBu，〜tBu，和Bn）作为降冰片烯的钯催化氰基酯化反应的中间体
3. The molecular mechanism of palladium-catalysed cyanoesterification of methyl cyanoformate onto norbornene [J] . Ishitsuka Takuya, Okuda Yasuhiro, Szilagyi Robert K., Dalton transactions: An international journal of inorganic chemistry . 2016,第18期

机译：钯催化氰基甲酸甲酯氰基酯化在降冰片烯上的分子机理
4. Preparation and Structures of Alkoxycarbonyl(cyano)palladium(II) Complexes as Intermediates of the Palladium-Catalyzed Cyanoesterification of Norbornenes [C] . Yasushi Nishihara, Mitsuru Miyasaka, Yoshiaki Inoue Symposium on Organometallic Chemistry . 2007

机译：烷氧基羰基（氰基）钯（II）复合物作为钯催化氰基酯化的中间体的烷氧基羰基（Cyano）钯（II）复合物的制备和结构
5. Development of Palladium-Catalyzed Alkene Difunctionalization on Vinyl-Quinoline Type Substrate and Isolation of Pd-Alkyl Intermediate [D] . Xu, Lusha. 2016

机译：乙烯基喹啉类基质上钯催化烯烃双官能化的研究及钯烷基中间体的分离
6. Key Mechanistic Features in Palladium-Catalyzed Methylcyclopropanation of Norbornenes With Vinyl Bromides: Insights From DFT Calculations [O] . Fang Ying, Yutong Zhang, Chuyue Xiang, 1970

机译：降冰片烯与乙烯基溴化物的钯催化甲基环丙烷化的关键机理：从DFT计算中获得的见解
7. Palladium-Catalyzed Cyanoesterification of Norbornenes with Cyanoformates via the NC-Pd-COOR (R = Me and Et) Intermediate [O] . -1

机译：通过NC-PD-CoOR（R = ME和ET）中间体，钯催化氰基酯化烟蛋白的氰基酯化

Palladium-catalyzed cyanoesterification of norbornenes with cyanoformates via the NC-Pd-COOR (R = Me and Et) intermediate

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