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A MEMS-Based Catalytic Microreactor for a H$_{bf 2}$ O$_{bf 2}$ Monopropellant Micropropulsion System

机译:基于MEMS的H $ _ {bf 2} $ O $ _ {bf 2} $单推进剂微推进系统催化微反应器

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The next generation of miniaturized satellites (‘nanosats’) feature dramatically reduced thrust and impulse requirements for purposes of spacecraft attitude control and maneuvering. The present study is a joint computational and experimental design effort at developing a new MEMS-based microreactor configuration for incorporation into a monopropellant micropropulsion system. Numerical models of the gas phase catalytic decomposition in microchannel configurations are used to obtain critical sizing requirements for the reactor design. The computational results show that the length scales necessary for complete decomposition are compatible with MEMS-based designs; however, it is also found that the catalytic process is dominated by mass diffusion characteristics within the flow at this scale. Experimentally, a microscale catalytic reactor prototype has been designed and microfabricated using MEMS techniques. The reactor uses self-assembled ruthenium oxide nanorods grown on the wall surfaces as a catalyst. Experimental testing indicates that only partial decomposition of the hydrogen peroxide is achieved. Among the potential sources of the incomplete decomposition, a likely cause appears to be the inability of the H $_2$O$_2$ reactant stream to adequately wet the surface of the catalyst film composed of a high surface density of RuO $_2$ nanorods.
机译:下一代小型卫星(“ nanosats”)的功能大大降低了对航天器姿态控制和操纵的推力和冲力要求。本研究是一项联合的计算和实验设计工作,旨在开发一种新的基于MEMS的微反应器配置,以将其纳入单推进剂微推进系统中。微通道构型中气相催化分解的数值模型用于获得反应器设计的关键尺寸要求。计算结果表明,完全分解所需的长度尺度与基于MEMS的设计兼容。然而,还发现,在该规模下,催化过程受流内质量扩散特性的支配。在实验上,已经设计了微型催化反应器原型并使用MEMS技术进行了微制造。该反应器使用在壁表面生长的自组装氧化钌纳米棒作为催化剂。实验测试表明,仅实现了过氧化氢的部分分解。在不完全分解的潜在来源中,可能的原因似乎是H $ _ 2 $ O $ _ 2 $ 反应物流以充分润湿由高表面密度的RuO组成的催化剂膜的表面。 “> $ _ 2 $ 纳米棒。

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