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Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

机译:演示使用酰亚胺锂从氨中制氢-为小型质子交换膜燃料电池供电

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摘要

Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH(3) -> 3H(2) + N-2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides. (C) 2016 Elsevier B.V. All rights reserved.
机译:获得氨中固有的氢含量(NH3)有可能在未来无二氧化碳可持续能源供应中发挥非常重要的作用。廉价的轻金属酰亚胺和酰胺可在中等温度下有效地将氨分解为氢和氮(2NH(3)-> 3H(2)+ N-2),因此代表了按需生产氢的低成本方法。在此发现的基础上,本文介绍了将氨裂化装置与后反应器气体净化系统和小型PEM燃料电池集成在一起的方法,以创建第一个台式演示器,用于使用轻金属酰亚胺生产氢。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Journal of power sources》 |2016年第15期|138-147|共10页
  • 作者单位

    STFC Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England;

    Univ Oxford, Inorgan Chem Lab, South Parks Rd, Oxford OX1 3QR, England;

    STFC Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England;

    Arcola Energy Ltd, 24 Ashwin St, London E8 3DL, England;

    STFC Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England;

    STFC Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England;

    STFC Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England;

    STFC Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England|Univ Oxford, Inorgan Chem Lab, South Parks Rd, Oxford OX1 3QR, England;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Ammonia cracking; Demonstrator; Hydrogen production; PEM fuel cell; Lithium imide;

    机译:氨裂化示踪剂制氢PEM燃料电池酰亚胺锂;

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