Multiple-year black carbon measurements and source apportionment using Delta-C in Rochester, New York

摘要

Black carbon (BC), an important component of the atmospheric aerosol, has climatic, environmental, and human health significance. In this study, BC was continuously measured using a two-wavelength aethalometer (3 70 nm and 880 nm) in Rochester, New York, from January 2007 to December 2010. The monitoring site is adjacent to two major urban highways (1-490 and 1-590), where 14% to 21% of the total trafficwas heavy-dutydieselvehicles. The annualaverage BCconcentrations were 0.76 μg/m~3', 0.67μg/m~3, 0.60μg/m~3, and0.52 μg/m~3 in 2007, 2008, 2009, and 2010, respectively. Positive matrix factorization (PMF) modeling was performed using PM_(2.5) elements, sulfate, nitrate, ammonia, elemental carbon (EC), and organic carbon (OC) data from the U.S. Environmental Protection Agency (EPA) speciation network and Delta-C (UVBC_(370nm) - BC_(880nm)) data. Delta-C has been previously shown to be a tracer of wood combustion factor. It was used as an input variable in source apportionment models for the first time in this study and was found to play an important role in separating traffic (especially diesel) emissions from wood combustion emissions. The result showed the annual average PM_(2.5) concentrations apportioned to diesel emissions in 2007, 2008, 2009, and2010were 1.34μg/m~3, 1.25μg/m~3, 1.13μg/m~3, and 0.97 μg/m~3, respectively. The BC conditional probability function (CPF) plots show a large contribution from the highway diesel traffic to elevated BC concentrations. The measurements and modeling results suggest an impact of the U.S Environmental Protection Agency (EPA) 2007 Heavy-Duty Highway Rule on the decrease of BC and PM_(2.5) concentrations during the study period. Implications: This study suggests that there was an observable impact of the U.S EPA 2007 Heavy-Duty Highway Rule on the ambient black carbon concentrations in Rochester, New York. Aethalometer Delta-C was used as an input variable in source apportionment models and it allowed the separation of traffic (especially diesel) emissions from wood combustion emissions. Supplemental Materials: Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for additional details on the sampling location, the analyses of the aerosol data, and the alternative PMF analysis omitting Delta-C.