首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of 4,4′-[(1,3,5,7-tetra­oxo-1,3,3a,4,4a,5,7,7a,8,8a-deca­hydro-4,8-etheno­pyrrolo­[3,4-f]iso­indole-2,6-di­yl)bis­(methyl­ene)]bis­(pyridin-1-ium) dinitrate
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Crystal structure of 4,4′-[(1,3,5,7-tetra­oxo-1,3,3a,4,4a,5,7,7a,8,8a-deca­hydro-4,8-etheno­pyrrolo­[3,4-f]iso­indole-2,6-di­yl)bis­(methyl­ene)]bis­(pyridin-1-ium) dinitrate

机译:4,4'-[((1,3,5,7-tetraoxo-1,3,3a,4,4a,5,7,7a,8,8a-十氢-4,8-​​ethenopyrrolo [3, 4-f]异吲哚-2,6-二基)双(亚甲基)双(吡啶-1-鎓)二硝酸盐

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摘要

In the title salt, C24H22N4O42+·2NO3−, the cation is U-shaped with the two iso­indole dione rings inclined to one another by 60.41 (13)°, while the two outer pyridine rings are inclined to one another by 2.77 (12)°. The dihedral angles between the pyridine ring and the adjacent iso­indole dione ring are 71.82 (12) and 86.44 (13)°. In the crystal, each nitrate anion is linked to a protonated pyridine ring by N—H⋯O hydrogen bonds. These units are linked by a series of C—H⋯O hydrogen bonds, forming a three-dimensional structure.
机译:在标题盐C24H22N4O42 +·2NO3-中,阳离子为U形,两个异吲哚二酮环彼此倾斜60.41(13)°,而两个外吡啶环彼此倾斜2.77(12)° 。吡啶环与相邻的异吲哚二酮环之间的二面角为71.82°(12)和86.44°(13)°。在晶体中,每个硝酸根阴离子通过N-H = O氢键连接到质子化吡啶环上。这些单元通过一系列CHOH氢键连接,形成三维结构。

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