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Designing of cardanol based polyol and its curing kinetics with melamine formaldehyde resin

机译:腰果酚基多元醇的设计及其与三聚氰胺甲醛树脂的固化动力学

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AbstractCommercially used industrial baking enamels consist of alkyd or polyester resin with melamine formaldehyde. These resins are mainly derived from fossil resources. Considering growing environmental legislation regarding use of petroleum based raw materials, utilization of renewable resources to synthesize various chemistries can be the only obvious option as far as academia and industries are concerns. The present work deals with exploration of one of the natural resources (Cardanol) for polyol synthesis, its characterization (FTIR and NMR) and its curing behavior with melamine formaldehyde resin by differential scanning calorimetry (DSC). The optimized formulations from DSC study were further evaluated for general coating properties to study the suitability of developed polyol for industrial coating application. The experimental studies revealed that melamine content in the curing mixtures and thereby developed crosslinking density played an important role in deciding the coatings properties.
机译:摘要商业上使用的工业烤瓷漆由醇酸或聚酯树脂与三聚氰胺甲醛组成。这些树脂主要来自化石资源。考虑到日益增长的有关使用石油基原材料的环境法规,就学术界和工业而言,利用可再生资源合成各种化学物质可能是唯一明显的选择。本工作涉及通过差示扫描量热法(DSC)探索用于多元醇合成的一种天然资源(腰果酚),其表征(FTIR和NMR)及其与三聚氰胺甲醛树脂的固化行为。进一步评估了DSC研究的优化配方的一般涂料性能,以研究开发的多元醇在工业涂料中的适用性。实验研究表明,固化混合物中三聚氰胺的含量以及由此产生的交联密度在决定涂料性能方面起着重要作用。

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