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An enantiopure Fe~（Ⅲ）4 single-molecule magnet

机译：对映纯Fe〜（Ⅲ）4单分子磁体

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摘要

A pair of enantiopure star-shaped Fe~(Ⅲ)4 clusters were constructed from simple chiral ligands. AC field frequency dependence and a hysteresis loop, which are very important features of SMMs, were observed. Circular dichroism (CD) spectra demonstrated that the chirality was successfully transferred from the ligand to the coordination environment of Fe~(3+) ions.
机译：由简单的手性配体构成一对对映纯的星形Fe〜（Ⅲ）4簇。观察到交流磁场频率依赖性和磁滞回线，这是SMM的非常重要的特征。圆二色性（CD）谱表明手性已成功地从配体转移到Fe〜（3+）离子的配位环境。

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  • 来源
    《Chemical Communications》 |2011年第28期|p.8049-8051|共3页
  • 作者

    Yuan-Yuan Zhu; Xiao Guo; Chang Cui; Bing-Wu Wang; Zhe-Ming Wang; Song Gao;

  • 作者单位

    Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, P. R. China;

    Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, P. R. China;

    Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, P. R. China;

    Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, P. R. China;

    Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, P. R. China;

    Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, P. R. China;

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  • 入库时间 2022-08-17 13:22:36

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