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A hybrid with uniaxial negative thermal expansion behaviour: the synergistic role of organic and inorganic components

机译：具有单轴负热膨胀行为的混合材料：有机和无机成分的协同作用

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摘要

Presented is an inorganic-organic hybrid compound Mn_2(api)Sb_2S_5 with uniaxial NTE behaviour. The NTE of 1 reflects a strong synergistic role of organic and inorganic components, which results from the novel zigzag linkage of intertamellar organic ligands. An "elevator-platform" expansion mechanism was proposed, with implications for future design of sensitive hybrid thermomechanical actuators.
机译：提出了一种具有单轴NTE行为的无机-有机杂化化合物Mn_2（api）Sb_2S_5。 NTE为1反映了有机和无机成分的强大协同作用，这是由层间有机配体的新型之字形连接引起的。提出了一种“电梯-平台”扩展机构，对敏感的混合热机械致动器的未来设计有影响。

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  • 来源
    《Chemical Communications》 |2014年第95期|14960-14963|共4页
  • 作者

    Kai-Yao Wang; Mei-Ling Feng; Liu-Jiang Zhou; Jian-Rong Li; Xing-Hui Qi; Xiao-Ying Huang;

  • 作者单位

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China ,College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, P. R. China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China;

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  • 入库时间 2022-08-17 13:16:43

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