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Superwetting fabrics towards multifunctional applications: Oil/water separation, anti-fouling and flame-retardance

机译:面向多功能应用的超湿织物:油/水分离,防污和阻燃

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Superwetting fabrics are promising materials for oil/water separation, but their poor thermal stability, easy to be contaminated and flammability severely restrict their cross-domain applications. Here we report multifunctional Ni(OH)(2)@fabrics with satisfyingly hierarchical structures via a simple hydrothermal method. Besides oil/water separation, Ni(OH)(2) coated fabrics also exhibit exceptional flame-retardancy and good thermal stability. The as-prepared fabrics possess superhydrophilicity/underwater superoleophobicity plus superoleophilicity/underoil superhydrophobicity and therefore could be directly used for oil/water separation containing both water/heavy oil mixture and water/light oil mixture. Moreover, superamphiphilic Ni(OH)(2)@fabric could also transform into in-air superamphiphobic after modification of low surface energy materials. Benefitting from the capacity of trapping liquids or air of synthesized hierarchical structures, superamphiphilic fabric presents underwater anti-oil impact performance while superamphiphobic fabric shows excellent in-air antifouling property. These multifunctional fabrics could greatly widen the application conditions of superwetting materials for oil/water separation and show huge potentials in cross-domain industrials.
机译:超湿织物是用于油/水分离的有前途的材料,但是它们的热稳定性差,容易被污染并且易燃性严重限制了它们的跨领域应用。在这里,我们通过简单的水热方法报告了具有令人满意的层次结构的多功能Ni(OH)(2)@织物。除油/水分离外,Ni(OH)(2)涂层织物还具有出色的阻燃性和良好的热稳定性。所制备的织物具有超亲水性/水下超疏油性加上超亲油性/欠油超疏水性,因此可直接用于包含水/重油混合物和水/轻油混合物的油/水分离中。此外,低表面能材料改性后,超两亲性的Ni(OH)(2)@织物也可能转变为空气中的超两性。得益于截留合成层次结构中的液体或空气的能力,超两亲织物具有水下抗油冲击性能,而超两亲织物则具有出色的空气防污性能。这些多功能织物可以大大拓宽超润湿材料用于油/水分离的应用条件,并在跨领域工业中显示出巨大的潜力。

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