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FeS2/C Nanowires as an Effective Catalyst for Oxygen Evolution Reaction by Electrolytic Water Splitting

机译:FeS2 / C纳米线作为电解水分解制氧反应的有效催化剂

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摘要

Electrolytic water splitting with evolution of both hydrogen (HER) and oxygen (OER) is an attractive way to produce clean energy hydrogen. It is critical to explore effective, but low-cost electrocatalysts for the evolution of oxygen (OER) owing to its sluggish kinetics for practical applications. Fe-based catalysts have advantages over Ni- and Co-based materials because of low costs, abundance of raw materials, and environmental issues. However, their inefficiency as OER catalysts has caused them to receive little attention. Herein, the FeS /C catalyst with porous nanostructure was synthesized with rational design via the electrochemical activation method, which serves as a good catalytic reaction in the OER process. The FeS /C catalyst delivers overpotential values of only 291 mV and 338 mV current densities of 10 mA/cm and 50 mA/cm , respectively, after electrochemical activation, and exhibits staying power for 15 h.
机译:随着氢气(HER)和氧气(OER)的分解而进行的电解水分解是生产清洁能源氢气的一种有吸引力的方法。由于氧气在实际应用中的动力学缓慢,因此探索有效的,低成本的氧气放出电催化剂(OER)至关重要。铁基催化剂比镍基和钴基材料具有优势,这是因为其成本低廉,原材料丰富且存在环境问题。但是,由于它们作为OER催化剂的效率低下,因此很少受到关注。本文采用电化学活化法合理设计合成了具有多孔纳米结构的FeS / C催化剂,在OER过程中具有良好的催化作用。在电化学活化后,FeS / C催化剂的过电势值分别仅为291 mV和338 mV,电流密度分别为10 mA / cm和50 mA / cm,并表现出15 h的持久力。

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