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Plastic fats from sal mango and palm oil by lipase catalyzed interesterification

机译:脂肪酶催化的萨尔芒果和棕榈油中的塑料脂肪酯交换

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摘要

Speciality plastic fats with no trans fatty acids suitable for use in bakery and as vanaspati substitute were prepared by interesterification of blends of palm stearin (PSt) with sal and mango fats using Lipozyme TLIM lipase as catalyst. The blends containing PSt/sal or PSt/mango showed short melting range and hence are not suitable as bakery shortenings. Lipase catalysed interesterification extended the plasticity or melting range of all the blends. The blends containing higher proportion of PSt with sal fat (50/50) were harder having high solids at and above body temperature and hence cannot be used as bakery shortenings. The blends with PSt/sal (30–40/60–70) after interesterification showed melting profiles similar to those of commercial hydrogenated bakery fats. Similarly, the blends containing PSt/mango (30–40/60–70) after interesterification also showed melting profiles similar to those of commercial hydrogenated shortenings. The slip melting point and solidification characteristics also confirm the plastic nature of these samples. The improvement in plasticity after interesterification is due to formation of higher melting as well as lower melting triglycerides during lipase catalysed interesterification.
机译:通过使用Lipozyme TLIM脂肪酶作为催化剂,将棕榈硬脂精(PSt)与Sal和Mango脂肪的掺混物进行酯交换反应,制得适用于面包房并用作Vanaspati替代品的不含反式脂肪酸的特种塑料脂肪。包含PSt / sal或PSt /芒果的共混物显示出短的熔化范围,因此不适合用作烘焙起酥油。脂肪酶催化的酯交换作用扩大了所有共混物的可塑性或熔融范围。含有较高比例的PSt和Sal脂肪(50/50)的掺混物在室温及以上温度下具有较高的固体含量,因此较硬,因此不能用作烘焙起酥油。酯交换后与PSt / sal(30–40 / 60–70)的共混物显示出类似于商业氢化烘焙脂肪的熔融曲线。同样,酯交换后含PSt /芒果(30-40 / 60-70)的共混物的熔融曲线也类似于商业氢化起酥油。滑移熔点和固化特性也证实了这些样品的塑性。酯交换后可塑性的提高是由于在脂肪酶催化的酯交换过程中形成了较高的熔融度和较低的熔融甘油三酸酯。

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