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On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case

机译:动力学阻滞下过冷分子玻璃形成液的遍历性:邻三联苯的情况

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摘要

The dynamics of supercooled ortho-terphenyl has been studied using photon-correlation spectroscopy (PCS) in the depolarized scattering geometry. The obtained relaxation curves are analyzed according to the mode-coupling theory (MCT) for supercooled liquids. The main results are: i) the observation of the secondary Johari-Goldstein relaxation (β) that has its onset just at the dynamical crossover temperature TB (TM > TB > Tg); ii) the confirmation, of the suggestion of a recent statistical mechanical study, that such a molecular system remains ergodic also below the calorimetric glass-transition temperature Tg. Our experimental data give evidence that the time scales of the primary (α) and this secondary relaxations are correlated. Finally a comparison with recent PCS experiments in a colloidal system confirms the primary role of the dynamical crossover in the physics of the dynamical arrest.
机译:使用光子相关光谱法(PCS)在去极化散射几何学中研究了过冷的邻三苯的动力学。根据模式耦合理论(MCT)对过冷液体分析了获得的弛豫曲线。主要结果是:i)观察到第二次Johari-Goldstein弛豫(β)仅在动态交叉温度TB(TM> TB> Tg)时才开始出现; ii)根据最近的统计力学研究的建议,证实了这样的分子系统在低于量热玻璃化转变温度Tg的情况下仍保持遍历。我们的实验数据提供了证据,表明主要(α)的时间尺度与该次要弛豫之间存在相关性。最后,与胶体系统中最新的PCS实验进行比较,证实了动态交叉在动态阻滞物理学中的主要作用。

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