Crystal structure of bis­{24-di-tert-butyl-6-(iso­propyl­imino)­meth­ylphenolato-κ2NO}zinc di­chloro­methane mono­solvate

摘要

In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the Zn^II atom is N,O-chelated by two crystallographically independent salicyl­aldehyde imine ligands, leading to a distorted tetra­hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra­molecular non-classical C—H⋯O hydrogen-bonding inter­actions are observed. In the crystal, the complex mol­ecules stack into columns along the a axis. Di­chloro­methane solvent mol­ecules are situated in the voids of this arrangement.