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Development of a Polymer-Mediated Soybean Nanocomposite by Hot Melt Extrusion to Improve Its Functionality and Antioxidant Properties

机译:通过热熔挤出开发聚合物介导的大豆纳米复合材料以提高其功能性和抗氧化性能

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摘要

The poor bioaccessibility of the phenolic compounds of soybeans is a key challenge to developing functional food products. Therefore, a novel hydrophilic food-grade hydroxypropyl methylcellulose (HPMC) polymer was added to soybean to prepare a soybean food composite (SFC), in order to improve the soybean’s functionality. The SFC was prepared with soybean (95%) plus HPMC (5%) (w/w) mixes (HSE), as well as 100% soybean extrudate (SE), at 80 °C and 130 °C by a hot melt extrusion (HME) process. A non-extrudate 100% soybean material was considered as a control. It is observed that water solubility was significantly increased (35.18%), and particle size reached to nano-size (171.5 nm) in HSE at 130 °C compared to the control (7.14% and 1166 nm, respectively). The total phenolic, flavonoid, and single isoflavones content, including daidzin, daidzein, glycitein, genistein, and genistin was significantly increased in HSE at 130 °C compared to the control. The antioxidant properties were also significantly increased in HSE at 130 °C compared to the control, measured by 2,2-diphenyl-1 picryl hydrazyl (DPPH), a ferric reducing antioxidant power assay (FRAP), and the phosphomolybdenum method (PPMD). Finally, it is concluded that the HPMC polymer could be used as a novel excipient to develop nanocomposite via HME, in order to improve the functionality of soybean food products.
机译:大豆中酚类化合物的生物利用度差是开发功能性食品的关键挑战。因此,将一种新型的亲水食品级羟丙基甲基纤维素(HPMC)聚合物添加到大豆中,以制备大豆食品复合材料(SFC),以改善大豆的功能。 SFC由大豆(95%)加HPMC(5%)(w / w)混合物(HSE)以及100%大豆挤出物(SE)在80°C和130°C下通过热熔挤出制备(HME)流程。将非挤出的100%大豆材料视为对照。观察到,与对照(分别为7.14%和1166 nm)相比,在130°C的HSE中,水溶性显着增加(35.18%),并且达到纳米级(171.5 nm)。与对照相比,HSE在130°C下的总酚,类黄酮和单一异黄酮含量(包括大豆苷,大豆苷元,糖蛋白,染料木黄酮和染料木素)显着增加。在130°C的HSE中,与对照相比,抗氧化性能也显着提高,通过2,2-二苯基-1苄基酰肼(DPPH),铁还原抗氧化能力测定(FRAP)和磷钼法(PPMD)测定。最后,得出结论,HPMC聚合物可作为新型赋形剂,通过HME开发纳米复合材料,以改善大豆食品的功能。

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