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A Short Route to the Ester (±) HomoSarkomycin via Johnson-Claisen Rearrangement

机译：通过Johnson-Claisen重排到达酯（±）同源沙霉素的捷径

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Background:α-Methylene cycloalkanones are considered of interest because of their biological activity. Herein, in this paper the synthesis of (±) HomoSarkomycine Esters was described and characterized.

机译：背景：由于其生物活性，α-亚甲基环烷酮被认为是令人关注的。本文中，对（±）HomoSarkomycine Esters的合成进行了描述和表征。

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期刊名称 Bentham Open Access
作者
M Saied; Rafik Gatri; Abdullah Sulaiman Al-Ayed; Youssef Arfaoui; Mohamed Moncef El Gaied;
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年(卷),期 -1(14),3
年度 -1
页码 181–185
总页数 5
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专利

1. A Short Route to the Ester (+/-) HomoSarkomycin via Johnson-Claisen Rearrangement [J] . Saied Mhamed, Gatri Rafik, Al-Ayed Abdullah Sulaiman, Letters in organic chemistry . 2017,第3期

机译：通过Johnson-Claisen Reatrantandement致前往酯（+/-）Homosarkomycin的短途路线
2. Chiral vicinal diols as platforms for separable diastereomers in Johnson-Claisen rearrangement: a new short route to (-)-nor-canadensolide, (-)-canadensolide and (-)-sporothriolide [J] . Rodney A. Fernandes, Arun B. Ingle Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第10期

机译：手性邻位二醇作为Johnson-Claisen重排中可分离的非对映异构体的平台：（-）-canadensolide，（-）-canadensolide和（-）-孢霉内酯的新捷径
3. Chiral vicinal diols as platforms for separable diastereomers in Johnson-Claisen rearrangement: a new short route to (-)-nor-canadensolide, (-)-canadensolide and (-)-sporothriolide [J] . Rodney A. Fernandes, Arun B. Ingle Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第10期

机译：手性邻位二醇作为Johnson-Claisen重排中可分离的非对映异构体的平台：（-）-canadensolide，（-）-canadensolide和（-）-孢霉内酯的新捷径
4. Water Determines the Selectivity: Facile Room Temperature C-O Cleavage of P(III) Esters by Br?nsted Acids Leading to a Mild and Efficient Halide-Free Michaelis–Arbuzov Rearrangement [C] . Chunya Li, Jianqiu Zhang, Jingjing Ye 日本化学会春季年会講演予稿集 . 2018

机译：水决定了选择性：Br的选择性：Br的P（III）酯的C-O裂解乳酸的乳酸，导致无温和和高效的卤化物Michaelis-Arbuzov重排
5. Synthesis of Functionalized α,α-Dibromo Esters through Claisen Rearrangements of Dibromoketene Acetals and the Investigation of the Phosphine-Catalyzed [4 + 2] Annulation of Imines and Allenoates [D] . Dupper, Nathan John. 2017

机译：官能化α，α-Dibromo酯的合成通过二溴乙烯缩醛的Claisen重排和亚胺和甲烯酸盐的膦催化的[4 + 2]包围的研究
6. Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones [O] . Samuel L. Bartlett, Kimberly M. Keiter, Blane P. Zavesky, -1

机译：通过α-酮基酯衍生的多价多杂应对复制形成复杂的α-氨基酯
7. Ytterbium triflate (and trimethylsilyl triflate) catalyzed isomerization of glycidic esters to α-hydroxy-β,γ-unsaturated esters and their conversion into cyclopentanoids using Johnson-Claisen rearrangement [O] . R. Kumareswaran, Shatrughan P. Shahi, Shikha Rani, 2002

机译：三氟甲磺酸镱（和三甲基甲硅烷基三氟甲磺酸酯）催化缩水甘油酯异构化为α-羟基-β，γ-不饱和酯，并使用Johnson-Claisen重排将它们转化为环戊烷类

A Short Route to the Ester (±) HomoSarkomycin via Johnson-Claisen Rearrangement

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