首页> 中文期刊> 《中国有色金属学报(英文版)》 >以PEG为分散剂从废绿矾中回收Fe3O4

以PEG为分散剂从废绿矾中回收Fe3O4

         

摘要

The effect of PEG dispersant on the magnetic separation of magnetite (Fe3O4) synthesized from ferrous sulfate solution via co-precipitation method with calcium hydroxide as the precipitant was investigated. The results indicated that a PEG dispersant could significantly affect Fe3O4 recovery. Adding PEG during the preparation of Fe3O4 was unfavorable for Fe3O4 recovery. When the PEG-6000 concentration was increased from 0 to 8 g/L, the iron grade and median particle size of the Fe3O4 product decreased from 65.58% and 2.35 μm to 57.79% and 1.35 μm, respectively. However, adding PEG during the wet milling of the mixed product promoted the subsequent recovery of Fe3O4. When the amount of PEG-200 increased from 0% to 4% of the powder mass, the grade of iron in the Fe3O4 product increased from 65.58% to 68.32%. While the relative molecular mass of PEG at an amount of 4% of the powder mass increased from 200 to 20000, the grade of iron was reduced from 68.32% to 66.70%.%以CaOH为沉淀剂通过共沉淀从绿矾溶液中回收Fe3O4,研究分散剂PEG对Fe3O4磁分离的影响.结果表明,分散剂PEG对Fe3O4的回收有显著影响.在Fe3O4制备过程中添加PEG不利于Fe3O4的回收.当PEG-6000浓度从0增加到8 g/L时,Fe3O4产品的铁品位从65.58%降至57.79%,中值粒径从2.35μm降至1.35μm.然而,在混合产物的湿磨过程中添加PEG可促进随后的Fe3O4回收.当PEG-200用量从粉末质量的0%增加到4%时,Fe3O4产物中铁的品位从65.58% 升高到68.32%.当PEG-200用量为4%时,改变PEG相对分子质量从200增加到20000,Fe3O4产物中铁品位从68.32%降至66.70%.

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