循环伏安法验证有机碘试剂氧化下偶联反应的机理

摘要

利用循环伏安法测定了有机碘试剂作用下交叉偶联反应中两种反应底物的氧化还原电位,通过比较两种底物的氧化电位,确定了偶联反应机理的优势路径。%By use of cyclic voltammetry,we analyzed the oxidation potential of two substrates in the cross-coupling reaction oxidated by hypervalent Iodine.By comparing the oxidation potential we confirmed the real pathway of the cross-coupling reaction mechanism.