The use of shallow water covers for containing sulphide bearing mine tailings in non-arid climates has gained importance over the years due largely to the low diffusivity and solubility of oxygen in water, 2 x 10 -9 m2 s-1 and 8.6 g m -3 at 25°C compared to that in air of 1.78 x 10 -5 and 285 g m-3. As oxygen is one of the key factors in the oxidation of reactive iron bearing sulphide minerals present in the tailings, water covers provide an effective control measure. For water covers to be effective there should be no stirring or resuspension of the bed tailings. However, this seldom happens, as there are many variables in the field that would contribute to the resuspension of tailings. These variables include water level fluctuations and water circulation, and duration and velocity of winds, fetch (the distance along the pond over which wind blows from a certain direction), wave characteristics, sediment compaction and cohesion, and topography of the area.; In this thesis, based on information from eleven mine tailings sites in Canada, Scandinavia and elsewhere existing gaps in shallow water cover design including the problems of wind-induced erosion and resuspension of bottom tailings and cohesive nature of mine tailings were highlighted. Measurements of wind velocity and wave heights at two mine tailings sites in New Brunswick and Ontario, Canada, were conducted. The calculated bottom shear stresses using measured wave height exceeded the critical shear stress for erosion of bottom tailings at wind speeds higher than 9 ms-1. Sediment traps data at the two sites confirmed that resuspension was not a function of depth and wind generated stresses alone, but depended on other factors (for example, cohesion of tailings particles). An Erosion-Transportation-Accumulation (ETA) diagram was then used to confirm the areas of erosion, transportation and accumulation at these sites.; For the first time, the concept of cohesive sediment erosion and resuspension was applied to sulphide mine tailings.; The pH in the reactor tank dropped from neutral to 3.5 over sixteen months while that of the control tank fluctuated about neutral. The electrical conductivity of the water cover in the reactor tank was 2800 muS.cm-1 compared to 1600 muS.cm-1 in the control tank at the end of the experiments. Similarly, calcium, sulphate, manganese, and ferrous iron concentrations in the reactor tank were 600, 1730, 33, and 26.4 mgL -1 respectively compared to the corresponding values of 400, 860, 6.85 and 0.09 mgL-1 in the control tank. (Abstract shortened by UMI.)
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机译:多年来,由于氧气在水中的低扩散性和溶解性,2 x 10 -9 m2 s-1和8.6 gm -3的低扩散性,在非干旱气候中使用浅水覆盖物来容纳含硫化物的矿山尾矿已变得越来越重要。相比于空气中的1.78 x 10 -5和285 g m-3,温度为25°C。由于氧是尾矿中含铁反应性硫化物矿物氧化的关键因素之一,因此水覆盖提供了有效的控制措施。为使水盖有效,不得搅动或重悬床尾料。但是,这种情况很少发生,因为该字段中有许多变量会导致尾矿的重新悬浮。这些变量包括水位波动和水循环,风的持续时间和速度,取水(沿池塘从一定方向吹来的距离),波浪特征,沉积物压实和凝聚力以及该地区的地形。本文基于加拿大,斯堪的纳维亚半岛和其他地区的11个矿山尾矿场的信息,着重指出了浅水覆盖设计中存在的空白,包括风致侵蚀和底部尾矿的重悬以及矿山尾矿的粘性问题。在加拿大新不伦瑞克省和安大略省的两个矿山尾矿场进行了风速和波高的测量。在高于9 ms-1的风速下,使用测得的波高计算出的底部切应力超过了临界切应力,这是底部尾矿侵蚀的关键。这两个地点的沉积物陷阱数据证实,重悬并不是深度的函数,风的产生只是应力,而是取决于其他因素(例如,尾矿颗粒的内聚力)。然后使用侵蚀-运输-累积(ETA)图来确认这些地点的侵蚀,运输和累积区域。首次将粘性沉积物侵蚀和悬浮的概念应用于硫化矿尾矿。在16个月内,反应罐中的pH从中性降至3.5,而对照罐中的pH则在中性附近波动。实验结束时,反应罐中水盖的电导率为2800μS.cm-1,而对照罐中为1600μS.cm-1。同样,反应罐中的钙,硫酸盐,锰和亚铁的浓度分别为600、1730、33和26.4 mgL -1,而对照罐中的相应值为400、860、6.85和0.09 mgL -1。 (摘要由UMI缩短。)
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