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Incorporation of Er into GaN by in situ doping during halide vapor-phase epitaxy

机译:在卤化物气相外延过程中通过原位掺杂将Er掺入GaN中

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The incorporation of Er into GaN by in-situ doping during halide vapor phase epitaxy has been investigated. The NH_3, HCl, metallic Ga and Er were used as source as source materials, while N_2 was employed as a carrier gas. The GaN:Er films were obtained at different Ga/Er source temperaures. The SIMS analysis shows that the steady state Er doping concentration can be as high as 2x10~(18) cm~(-3). All in-situ Er-doped samples luminescence at 1.54 #mu#m due to the ~4I_(13/2) -> ~4I_(15/2) transition of Er~(3+) at both low (11K) and room temeprature. The higher the Ga/Er boat temeprature, the stronger the 1.54 #mu#m luminescence, implying a higher incorporation rate of Er into the GaN. The ~4I_(11/2) -> ~4I_(15/2) transition luminescence, centered around 980 nm, can also be detected at both low and room temeprature. The broad-spectrum PL measurements exhibited sharp bandedge luminescence without the presence of the yellow luminescence band.
机译:已经研究了在卤化物气相外延过程中通过原位掺杂将Er掺入GaN中的过程。 NH_3,HCl,金属Ga和Er被用作原料,而N_2被用作载气。在不同的Ga / Er源温度下获得了GaN:Er膜。 SIMS分析表明,稳态Er掺杂浓度可高达2×10〜(18)cm〜(-3)。由于在低(11K)和室温下Er〜(3+)的〜4I_(13/2)-> ~~ 4I_(15/2)跃迁,所有原位掺Er的样品在1.54#mu#m处发光temeprature。 Ga / Er舟形温度越高,1.54#μm的发光强度越强,这意味着Er掺入GaN的速率越高。还可以在低和室温条件下检测到〜4I_(11/2)->〜4I_(15/2)过渡发光,中心在980 nm附近。广谱PL测量显示出尖锐的带边缘发光,而没有黄色发光带。

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